MOFs consist of a nanoporous grid of both organic molecules and metal ions. MOFs take shape as the organic molecules push the metal ions apart, so that a regular pattern of tiny holes or nanopores develops. The size of the pores can be tuned at the nanoscale level. The internal surface of an MOF, formed by these pores, varies in size from 1000 to 5000m2 per gram of material.
Professor Rob Ameloot from the KU Leuven Centre for Surface Chemistry and Catalysis, said: “Researchers are examining the use of MOFs as catalysts to accelerate chemical reactions of guest molecules in the MOF pores. Another possible application is gas storage, as the internal surface of MOFs can hold large amounts.”
So far, some applications were not considered feasible due to the production procedure for MOFs. The conventional method involves lab-scale wet chemistry, the end result of which is a powder. For integrated, nanoscale applications, the particles of that powder are too large, while a method with solutions is not pure enough. In the case of gas sensors, for instance, the MOF material has to be deposited as a thin film over the surface of the electrical circuit. That is not possible if you use the conventional production procedure.
Lead researcher, Ivo Stassen set out to find a production method other than wet chemistry. He used vapours and gases instead of liquids. “Vapour-phase deposition is already a common method to produce high-tech devices. We are the first to use this method for the production of these highly porous materials. We first deposit layers of zinc and let them react with the vapour of the organic material. The organic material permeates the zinc, the volume of the whole expands, and it is fully converted into a material with a regular structure and nanopores”, he explained.
To fine-tune the procedure, the KU Leuven researchers are collaborating with the Leuven-based research centre imec, which specialises in nanoelectronics.
“This alternative production method opens up new possibilities for MOFs in terms of applications and industries. Chemical vapour deposition is a common technique in nanofabrication. Therefore, new MOF applications can be developed relatively quickly, such as gas sensors, nanochip components, and improved batteries,” Stassen concluded.
